等离子球化制备球形CaF<sub>2</sub>/BaF<sub>2</sub>共晶粉末*

陈杰1; 2; 安宇龙1; 赵晓琴1; 杨杰1; 2; 周惠娣1; 陈建敏1

引用本文:	陈杰1,2，安宇龙1，赵晓琴1，杨杰1,2 ，周惠娣1，陈建敏1.等离子球化制备球形CaF₂/BaF₂共晶粉末*[J].中国表面工程,2012,25(5):96~99
	CHEN Jie1, 2, AN Yulong1, ZHAO Xiaoqin1, YANG Jie1, 2, ZHOU Huidi1, CHEN Jianmin1.Plasma Spheroidization of CaF₂/BaF₂ Eutectic Powders[J].China Surface Engineering,2012,25(5):96~99

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等离子球化制备球形CaF₂/BaF₂共晶粉末*
陈杰1,2，安宇龙1，赵晓琴1，杨杰1,2 ，周惠娣1，陈建敏1
1. 中国科学院兰州化学物理研究所固体润滑国家重点实验室，兰州 730000； 2. 中国科学院北京研究生院，北京 100049

摘要:

探究了使用大气等离子喷涂设备制备适合热喷涂使用的球形CaF2/BaF2共晶粉末的可能性。68% BaF2、32%CaF2粉末（质量分数）经过1 100 ℃真空烧结后，形成致密的块状氟化物共晶。机械破碎后的氟化物共晶经过等离子焰流重熔后得到了球形的氟化物共晶。使用F141流动性和松装密度测定仪测量球化前后粉末的流动性和松装密度。采用扫描电子显微镜，XRD表征球化前后粉末的形貌和物相组成。结果表明：球化后的粉末呈现较好的球形，球化后粉末的流动性和松装密度较球化前也有较大的改善：球化后共晶粉末的流动时间为55.20 s/50 g，松装密度为1.89 g/cm3；另外，球化后共晶粉末还表现出良好的高温润滑性能：含有10% CaF2/BaF2共晶（质量分数）的镍基涂层在600 ℃和800 ℃的平均摩擦因数都小于0.3。

关键词: 等离子球化 CaF₂/BaF₂共晶热喷涂

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Plasma Spheroidization of CaF₂/BaF₂ Eutectic Powders

CHEN Jie1, 2, AN Yulong1, ZHAO Xiaoqin1, YANG Jie1, 2, ZHOU Huidi1, CHEN Jianmin1

1. State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000; 2. Graduate University of Chinese Academy of Sciences, Beijing 100049

Abstract:

The preparation process of spherical CaF2/BaF2 eutectic powders through plasma spray technology is investigated. The fluorides were first prepared by combining 68% BaF2 and 32% CaF2 to melt under vacuum at 1 100 ℃. The solidified fluorides were then crushed into powders for subsequent processing through plasma spheroidization. The microstructure and cystallographic phase of spherical CaF2/BaF2 eutectic powders were determined by SEM and Xray diffraction, while fluidity and apparent density were tested by F141flowmeter. Results show that the degree of sphericity of CaF2/BaF2 eutectic powders increases after spheroidizing, the fluidity and apparent density of spheroidal fluorides are 55.20 s/50 g and 1.89 g/cm3 respectively. In addition, spheroidal CaF2/BaF2 eutectic powders present good high temperature lubrication property，which can reduce the friction coefficient of Nibased composite coating at high temperature. The friction coefficients of Nibased composite coatings containing 10% CaF2/BaF2 eutectic at 600 ℃ and 800 ℃ are less than 0.3 in the experimental condition.

Key words: plasma spheroidization CaF₂/BaF₂ eutectic thermal spray